Rhenium, bromopentacarbonyl- - Names and Identifiers
Rhenium, bromopentacarbonyl- - Physico-chemical Properties
Molecular Formula | C5BrO5Re
|
Molar Mass | 406.16 |
Melting Point | 90°C (subl.) |
Water Solubility | Insoluble in water. |
Appearance | Morphological crystal, color off-white |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
MDL | MFCD00013295 |
Rhenium, bromopentacarbonyl- - Risk and Safety
Hazard Symbols | T - Toxic
|
Risk Codes | R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 - After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
|
UN IDs | UN 3288 6.1/PG 3 |
WGK Germany | 3 |
HS Code | 29310099 |
Hazard Class | 6.1 |
Packing Group | II |
Rhenium, bromopentacarbonyl- - Upstream Downstream Industry
Rhenium, bromopentacarbonyl- - Introduction
RHENIUM PENTACARBONYL BROMIDE(Rhenium pentacarbonyl bromide) is an organometallic compound with the chemical formula ReBr(CO)5.
Nature:
RHENIUM PENTACARBONYL BROMIDE is a yellow to dark red solid, soluble in organic solvents such as ether and carbon tetrachloride, but insoluble in water. It is sensitive to air and moisture and needs to be stored under an inert atmosphere.
Use:
RHENIUM PENTACARBONYL BROMIDE can be used as a catalyst for metal organic synthesis and catalytic reactions. It is commonly used in C- H bond activation reactions, hydrogenation and carbonylation reactions.
Method:
The method for preparing RHENIUM PENTACARBONYL BROMIDE is usually achieved by the reaction of PENTACARBONYL RHENIUM BROMIDE and sodium BROMIDE. The reaction was carried out by stirring a solution of rhenium pentacarbonyl bromide and sodium bromide in ethanol at room temperature and then extracting the product with ether.
Safety Information:
RHENIUM PENTACARBONYL BROMIDE requires attention to its radioactivity when used. In view of its sensitivity to air and moisture, it is necessary to operate under an inert atmosphere when used. In addition, RHENIUM PENTACARBONYL BROMIDE has certain toxicity and should be handled in accordance with safe operating procedures. It is best to use RHENIUM PENTACARBONYL BROMIDE under the guidance of a chemical professional.
Last Update:2024-04-10 22:29:15